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[Umich] COE Core/CHEM 130 (General Chemistry)

[Notes] Ch.E Essentials: Units, Measurement, and Problem Solving

by Class of 26' Yuri Hong 2022. 9. 28.

E.3 Units of measurement

 

1. SI prefixes 

* 표를 잘보고 두번 체크하기.

* 과정 누락하기 말기

1. A note about area (length squared) and volume (length cubed):

When you cube or square the unit, you must do the same to the value. 

1m = 100 cm, 1m^3 = (100cm)^3 = 1,000,000 cm3, 1m^3 = 1X10^6 cm^3 

 

Ex)  A cube has an edge length of 7 cm. If it is divided into 1 cm cubes, how many 1 cm cubes are there? 

volume = l*w*h = 7cm*7cm*7cm = 343 cm^3 ( = 3.43*10^-3)

2. Temperature Scales

 

3. Vocabulary

(1) Accuracy: how close is a measurement to the actual value? 

(2) Precision: how reproducible is the measurement? 

(3) Systematic error: all values are too high or low 

(4) Random error: equal probability high and low 

E.4 Significant figures

1. Counting sig fig

(1) Exact numbers: infinite sig fig Ex) pi, e, counted numbers, conversion factors

(2) Nonzero : always sig fig Ex) 56, 34, …

(3) Zeros:

-- Leading Zeros: not sig EX) 0.00000006 => 1 sig

-- Interior (captive): sig Ex) 306 => 3 sig

--Trailing zeros: sig only if there is a decimal point

* trailing zeros w/o a decimal point are insignificant or ambiguous.

Ex) 30.0 => 3 sf, 30 => ambiguous

 

2. Calculation rules

(1) Multiplication / division: the fewest sig fig

(2) Addition / subtraction: the fewest decimal places

(3) Rounding rules: >=5, round up, <5 keep

 

Ex) (9.18 + 9.2 + 9.157) / 3 = 9.179 => report: 9.2 

3 is the exact number, it will not affect the s.f. 

9.2 is the smallest number of s.g. so report tenth place. 

 

Ex) 2. 5110 x 21.20 / (44.11 + 1.223) 

 

* Always round at the end, x cut digits at every step.

* 계산 가장 작은 (곱셈) 찾기, decimal point (덧셈) 찾기

* exact number sig fig 판단하기

 

E.5 Density

1. Density can be used to identify a substance.

2. Density depends on temperature and does not depend on the amount of substance (intensive property). 

=> unit: g/mL (g/cm^2), g/L

* 단위 환산하는 과정에서 0 개수 주의 하기

Practice: A small airplane takes on 245 L of fuel. If the density of the fuel is 0.821 g/mL what mass of fuel has the airplane taken on? 

E. 6 Energy

1. Energy: capacity to do work (force through a distance)

2. The total E of an object: the sum of Kinetic E (associated with motion) & Thermal E (associated with object's temperature) & Potential E (associated with object's composition) 

=> systems with high potential E tend to lower their PE to become more stable. 

3. Law of conservation of Energy: In a process, energy is neither created nor destroyed.

(1) Exothermic: system loses E, change in E is negative.

(2) Endothermic: system gains E, change in E is positive.

4. Units of Energy

KE = 1/2mv^2 | Units: (kgm^2)/s^2 

1(kgm^2)/s^2 = 1 Joule

1 cal = 4.184J

1000 cal = 1 kcal = 1 Cal (nutritional) 

E.7,8,9  Problem Solving

1. 계산 과정 명확하게 쓰기.

2. 계산기 실수하지 말고 계산 번씩 확인

3. 문제 제대로 읽고 파악한 계산  

 

Ex) Convert 1.37 ounces of silver to milligrams of silver, given 1 oz = 28.35 g 

 

Practice: A house has an area of 1,235 ft^2. What is the area in km^2? 

Practice: A cylinder has a length of 10.0 cm, a radius of 1.0 cm, and a mass of 3.0 g. What is the density of the cylindrical substance in g/cm3? V_cylinder = 𝜋𝜋r^2h 

Practice: Polluted air can have carbon monoxide (CO) levels of 15.0 ppm. An average human inhales about 0.50 L of air per breath and takes about 20 breaths per minute. How many milligrams of carbon monoxide does the average person inhale in an 8-hour period in this level of carbon monoxide pollution? Assume that the CO has a density of 1.2 g/L. (Hint: 15.0 ppm CO means 15.0 L CO per 106 L air.) 

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